I have heard about this for years on Jeep forums. Not on the boating forums though, strangely enough. And until today though, I've never tried it.
Before I hauled the seized engine from Chopstick II (the new boat) to the scrap yard, I pulled off all the useful parts. One of them is the exhaust riser elbow. Pretty rusty though:
There might also be a crack at the outlet, which looks pretty badly corroded.
So the technique I am using is electrolysis. I put three pieces of rebar into an old 5-gallon plastic bucket, wire-brushed off the rust on the rebar at the top of the bucket so I would have good contact points to attach some copper wire to connect them all "electrically." They will serve as the anodes:
Next I filled the bucket with about 4 gallons of water and added 1/3 cup of washing soda. I then put a coat hanger through the exhaust riser and suspended the part in the middle of the solution, not touching the rebar anodes. The part then becomes the cathode:
Finally, I connected my battery charger's positive clip to the rebar anodes and the negative clip to the coat hanger suspending the part. When I turned on the battery charger (set at the low, 2-amp, charge level), current began flowing and little bubbles of hydrogen and oxygen gas immediately started flowing up and stirring the solution. A bit of rusty scum is starting to build up on the surface:
I'll leave it like that for a few hours, then pull the part out and examine it. More later.....